Paisley, 31, earned his first European Tour title at the BMW SA Open in January.
The leaderboard at the end of play had a distinctly global flavour with six different nationalities filling the first seven places.
He's making just his second start of the year this week at the WGC-Mexico Championship and already looks in mid-season form, posting a first-round seven-under 64 to grab the solo lead. Fifth-place finishes at Abu Dhabi and Dubai saw him punch his ticket to his first elite World Golf Championships event at the Club de Golf Chapultepec.
Starting at the 10th Dunne was in trouble early on with bogeys at three of his first five holes before he pulled a shot back thanks to a magnificent approach to the 16th - his eighth hole - which spun back and lipped out of the hole, nearly going in for an eagle two.
A costly late bogey has seen Marc Leishman drop out of the top 10 but the Victorian is still well placed after the opening round of the WGC Mexico Championship. I've got a nice little cut going with it. "To be up there playing so well and competing with guys like this is fantastic".
"I didn't want to come here and just be happy to be part of it and just make up the numbers. The way I hit it, I probably should not have shot 2 under".
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"I'm very confident with my driver at the moment", he said.
"I gave myself a lot of chances but they're tough greens to putt on and to hole as many putts as I did, I'm delighted".
Defending champion Dustin Johnson emerged from a roller-coaster round with a two-under 69.
The South African veteran had five birdies and an eagle on the 15th hole to cap a bogey-free day at Chapultepec Golf Club in Mexico City.
In fact, there were just two players from the top 10 in the World Ranking, No. 2 Jon Rahm (seventh) and No. 7 Rickie Fowler (tied for eighth), among the top 10 when play finally concluded in fading light after a 30-minute lightning delay. It's just that since their inception, the World Golf Championship events have largely been the domain of the game's most recognizable players, a dependable catalyst that produces predictably impressive contenders and champions.